Critical Roles of Chalcogenide Anion on Strengthening Stability of Ni 2 Mo 6 Te 8 for Almost Exclusive Electrocatalysts Nitrate to Ammonia Conversion: Human Oversight and Decision Accountability

Authors

  • Clayton Roberts Author
  • Dawson Morgan Author
  • Emmett Foster Author

Keywords:

electrocatalytic materials, human oversight and decision accountability, evidence synthesis, reproducibility, research evaluation

Abstract

Human oversight is meaningful when intervention points, responsibility, escalation paths, and the evidence available to decision makers are explicitly defined. This structured evidence review evaluates "Critical Roles of Chalcogenide Anion on Strengthening Stability of Ni 2 Mo 6 Te 8 for Almost Exclusive Electrocatalysts Nitrate to Ammonia Conversion" alongside nine author-disjoint, topically matched publications in electrocatalytic materials. It compares construct definitions, evaluation choices, operating assumptions, and reported limitations instead of treating bibliographic similarity as empirical equivalence. Viewed through human oversight and decision accountability, the map separates claims supported by the available record from questions that still require full-text extraction, replication, or new experiments. The synthesis is interpretive rather than meta-analytic and therefore does not present a pooled effect estimate or a new causal result. The resulting agenda specifies reviewer authority, override logging, escalation procedures, and evaluation of automation bias.

References

  1. Xia, F., Li, B., Liu, Y., Tan, H., An, B., Gao, S., Marks, T.-J., & Cheng, Y. (2024). Critical Roles of Chalcogenide Anion on Strengthening Stability of Ni 2 Mo 6 Te 8 for Almost Exclusive Electrocatalysts Nitrate to Ammonia Conversion. Advanced Functional Materials, 34(14), 2312079. https://doi.org/10.1002/adfm.202312079
  2. Li, D., Liu, X., Geng, C., Gao, W., Zhang, L., & Liang, J. (2026). Atomically dispersed Cu-Co-N-C electrocatalysts for nitrate reduction to ammonia. Journal of Electroanalytical Chemistry, 1009, 119993. https://doi.org/10.1016/j.jelechem.2026.119993
  3. Niu, Z., & Wang, G. (2025). Rational electrocatalyst design for selective nitrate reduction to ammonia. Chemical Physics Reviews, 6(1). https://doi.org/10.1063/5.0230248
  4. Luo, X., Han, W., Du, W., Huang, Z., Jiang, Y., & Zhang, Y. (2020). Ordered mesoporous carbon with atomically dispersed Fe-Nx as oxygen reduction reaction electrocatalyst in air-cathode microbial fuel cells. Journal of Power Sources, 469, 228184. https://doi.org/10.1016/j.jpowsour.2020.228184
  5. Duan, J., Xue, D., Gong, T., Hu, J.-S., & Zhang, J.-N. (2025). Electronic Engineering of Atomically Dispersed Low/Non-Platinum Metal Electrocatalyst to Improve Oxygen Reduction Reaction Durability for Proton Exchange Membrane Fuel Cells. Renewables, 3(4), 203-221. https://doi.org/10.31635/renewables.025.202500094
  6. Guan, J., Geng, L., Ouyang, B., Xu, L., Deng, Y., & Xu, B. (2025). Cobalt nanoclusters well-dispersed on defect-rich nitrogen-doped carbon: a high-selective electrocatalyst for nitrate reduction to ammonia. Journal of Power Sources, 658, 238282. https://doi.org/10.1016/j.jpowsour.2025.238282
  7. Liu, L., Zheng, S.-J., Chen, H., Cai, J., & Zang, S.-Q. (2024). Tandem Nitrate‐to‐Ammonia Conversion on Atomically Precise Silver Nanocluster/MXene Electrocatalyst. Angewandte Chemie, 136(8). https://doi.org/10.1002/ange.202316910
  8. Wu, Z., Wang, Y., Cao, Y., Wang, B., Sun, Z., Yang, J., & Li, Y. (2023). Ammonia Tolerance of Atomically Dispersed Single Metal Site Catalysts: Mechanistic Understanding and High‐Performance Oxygen Reduction Electrocatalysis. Advanced Functional Materials, 33(32). https://doi.org/10.1002/adfm.202301084
  9. Xu, Y.-Z., Abbott, D., Dürr, R., Ngoc Huan, T., & Mougel, V. (2024). A Bio-inspired Dendritic MoOx Electrocatalyst for Efficient Electrochemical Nitrate Reduction to Ammonia. . https://doi.org/10.26434/chemrxiv-2024-4gxn8
  10. Gonzaga, I.-M.-D., Almeida, C.-V.-S., & Mascaro, L.-H. (2026). Sustainable nitrate reduction to ammonia using CuO-TiO2 electrocatalyst. Catalysis Today, 474, 115828. https://doi.org/10.1016/j.cattod.2026.115828

Downloads

Published

2026-08-27

Issue

Section

Review Article